123289-72-5Relevant academic research and scientific papers
Asymmetric Heck reaction of alkenyl iodides in the presence of silver salts. Catalytic asymmetric synthesis of decalin and functionalized indolizidine derivatives
Sato,Nukui,Sodeoka,Shibasaki
, p. 371 - 382 (1994)
Decalin derivatives 3 (up to 80% ee) and indolizidine derivative 6 (up to 86% ee) have been synthesized by an asymmetric Heck reaction starting with prochiral alkenyl iodides 1 and 4, respectively. The important role of silver salts in the asymmetric Heck
Catalytic Asymmetric C-C Bond Formation: Asymmetric Synthesis of cis-Decalin Derivatives by Palladium-Catalyzed Cyclization of Prochiral Alkenyl Iodides
Sato, Yoshihiro,Sodeoka, Mikiko,Shibasaki, Masakatsu
, p. 4738 - 4739 (2007/10/02)
A catalytic asymmetric synthesis by the use of a Heck-type reaction has been realized for the first time, giving the cis-decalin derivative 5 in up to 46percent ee.
