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3,4-bis((3,5-bis(trifluoromethyl)phenyl)amino)cyclobut-3-ene-1,2-dione is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1233032-05-7

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1233032-05-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1233032-05-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,3,3,0,3 and 2 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1233032-05:
(9*1)+(8*2)+(7*3)+(6*3)+(5*0)+(4*3)+(3*2)+(2*0)+(1*5)=87
87 % 10 = 7
So 1233032-05-7 is a valid CAS Registry Number.

1233032-05-7Downstream Products

1233032-05-7Relevant articles and documents

Squaramide–Quaternary Ammonium Salt as an Effective Binary Organocatalytic System for Oxazolidinone Synthesis from Isocyanates and Epoxides

Rostami, Ali,Ebrahimi, Amirhossein,Husband, John,Anwar, Muhammad Usman,Csuk, Rene,Al-Harrasi, Ahmed

, p. 1881 - 1895 (2020/03/13)

Squaramide–quaternary ammonium salt is illustrated as a simple, tunable, and competent metal-free binary catalytic platform for the atom-economic conversion of epoxides and isocyanates into oxazolidinones. Although, various metal catalysts have been employed for the title reaction, application of organocatalysis is scarce. At first, a rational survey of catalytic activity of several air-stable and architecturally distinct squaramides was undertaken. Thereafter, the impact on catalytic capability of different parameters, such as temperature, catalyst loading, and nature of nucleophiles, was examined. This binary organocatalytic system for the oxazolidinone synthesis, composed of a squaramide entity along with a suitable halide anion, was applied to the challenging conversion of a plethora of alkyl- and aryl-substituted epoxides– including disubstituted and enantioenriched ones– and isocyanates into the corresponding oxazolidinones in high-to-excellent yields. The time-dependent formation of oxazolidinone from epoxide and isocyanate was monitored by FTIR-ATR and 1H NMR spectroscopy and the scalability of this process was also described. In light of 1H NMR experiment, a hydrogen-bonding/anion-binding mechanism was proposed wherein the nucleophilic ring-opening operation, and oxo- and carbamate-anions stabilization occur cooperatively towards isocyanate fixation.

Hydrogen-Bond Catalysis of Imine Exchange in Dynamic Covalent Systems

Schaufelberger, Fredrik,Seigel, Karolina,Ramstr?m, Olof

supporting information, p. 15581 - 15588 (2020/10/02)

The reversibility of imine bonds has been exploited to great effect in the field of dynamic covalent chemistry, with applications such as preparation of functional systems, dynamic materials, molecular machines, and covalent organic frameworks. However, acid catalysis is commonly needed for efficient equilibration of imine mixtures. Herein, it is demonstrated that hydrogen bond donors such as thioureas and squaramides can catalyze the equilibration of dynamic imine systems under unprecedentedly mild conditions. Catalysis occurs in a range of solvents and in the presence of many sensitive additives, showing moderate to good rate accelerations for both imine metathesis and transimination with amines, hydrazines, and hydroxylamines. Furthermore, the catalyst proved simple to immobilize, introducing both reusability and extended control of the equilibration process.

Supramolecular relay-control of organocatalysis with a hemithioindigo-based molecular motor

Grill, Kerstin,Dube, Henry

supporting information, p. 19300 - 19307 (2020/11/13)

Integration of individual molecular components such as molecular motors or switches into larger meta-functional systems represents a current challenge at the forefront of molecular machine research. Here we present a modular supramolecular approach to relay the photoinduced geometry changes of a hemithioindigo based molecular motor into catalytic efficiency of a chemical reaction. Using the intrinsic chemical nature of the motor for recognition of different hydrogen-bonding organocatalysts a greater than 10-fold modulation in binding affinity is achieved upon photoisomerization. This change in affinity is then translated effectively into control of catalytic competence of the organocatalysts without direct interference by the motor. As an example the organocatalysed Michael addition reaction between nitrostyrene and 3-methoxy-dimethyl aniline was modulated in situ by visible light irradiation. Thus, dynamic and reversible remote control of catalytic processes by the switching capacity of a hemithioindigo molecular motor is established in a multicomponent chemical system. The high intrinsic modularity of this approach presents further advantages, e.g., for easy tailoring of conditions or facile exchange of catalysts and reactions. These results represent a first stepping stone into integrated chemical networks regulated by molecular machines in a fully dynamic way.

Thiosquaramides: PH switchable anion transporters

Busschaert, Nathalie,Elmes, Robert B. P.,Czech, Dawid D.,Wu, Xin,Kirby, Isabelle L.,Peck, Evan M.,Hendzel, Kevin D.,Shaw, Scott K.,Chan, Bun,Smith, Bradley D.,Jolliffe, Katrina A.,Gale, Philip A.

, p. 3617 - 3626 (2014/08/18)

The transport of anions across cellular membranes is an important biological function governed by specialised proteins. In recent years, many small molecules have emerged that mimick the anion transport behaviour of these proteins, but only a few of these

Squaramides as potent transmembrane anion transporters

Busschaert, Nathalie,Kirby, Isabelle L.,Young, Sarah,Coles, Simon J.,Horton, Peter N.,Light, Mark E.,Gale, Philip A.

supporting information; experimental part, p. 4426 - 4430 (2012/06/04)

Square peg in a round ball: Squaramides are shown to be potent transmembrane anion transporters for both chloride and bicarbonate, performing better than the thiourea and urea analogues. Studies into the nature of this transport point to a mobile carrier mechanism, where the squaramide delivers the anion cargo across the lipid bilayer (see scheme, green sphere=anion). These drug-like molecules provide a platform for the development of a new generation of anion-transport systems. Copyright

N, N′ -Diarylsquaramides: General, high-yielding synthesis and applications in colorimetric anion sensing

Rostami, Ali,Colin, Alexis,Li, Xiao Yu,Chudzinski, Michael G.,Lough, Alan J.,Taylor, Mark S.

experimental part, p. 3983 - 3992 (2010/08/22)

Zinc trifluoromethanesulfonate promotes efficient condensations of anilines with squarate esters, providing access to symmetrical and unsymmetrical squaramides in high yields from readily available starting materials. Efficient access to electron-deficient diaryl squaramides has enabled a systematic investigation of the colorimetric anion-sensing behavior of a p-nitro-substituted squaramide. Its behavior differs in dramatic and unexpected ways from that of structurally similar p-nitroaniline-based ureas, an effect that highlights the remarkable differences in acidity between the squaramide and urea functional groups. Computational studies illustrating the enhanced hydrogen bond donor ability and acidity of squaramides in comparison to ureas are presented.

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