1233195-48-6

Basic information

• Product Name: C₄₃H₃₂Cl₂
• Synonyms: C₄₃H₃₂Cl₂
• CAS NO: 1233195-48-6
• Molecular Weight: 619.633
• Mol File: 1233195-48-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₃H₃₂Cl₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₃H₃₂Cl₂(1233195-48-6)
• EPA Substance Registry System: C₄₃H₃₂Cl₂(1233195-48-6)

Safety Data

• Hazardous Substances Data: 1233195-48-6(Hazardous Substances Data)

Upstream product

• 875928-76-0 1-(2-methyl-1-phenyl-3-(2,2-diphenylvinylidene)cyclopropyl)benzene 
• 90-97-1 4,4'-dichlorobenzophenone 

Relevant articles and documents

BF3·OEt2-catalyzed intermolecular reactions of yinylidenecyclopropanes with bis(p-alkoxyphenyl)methanols: A novel cationic 1,4-aryl-migration process

BF3·OEt2-catalyzed reactions of vinylidenecyclopropanes (VDCPs) 1 with bis(aryl)methanols 2 were thoroughly investigated. When VDCPs 1 reacted with electron-rich bis(aryl)methanols 2, diastereomeric retamers of indene derivatives formed in excellent yields by a novel cationic 1,4aryl migration between two carbon atoms and the subsequent intramolecular Friedel-Crafts reaction pathways in the presence of BF 3·OEt2 under mild conditions. As for electron-deficient or less-electron-rich bis(aryl)methanols 2, either trialkene products formed in good yields by direct deprotonation, or another type of indene derivative was produced by direct intramolecular Friedel-Crafts reaction, depending on the substituents on the cyclopropane of VDCPs. In addition, DFT calculations were carried out to explain the experimental results. Plausible mechanisms for all these transformations are proposed on the basis of the experimental and computational results.