1233218-76-2

Upstream product

• 61490-71-9 (2R)-(+)-1,2-hexadecanediol 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 

Downstream Products

• 1233218-77-3 C₂₄H₄₀O₃ 

Relevant academic research and scientific papers

Synthesis of immunostimulatory α- C -galactosylceramide glycolipids via sonogashira coupling, asymmetric epoxidation, and trichloroacetimidate- mediated epoxide opening

Stereocontrolled syntheses of α-C-GalCer (2) and its α-C-acetylenic analogue 6 were accomplished in high efficiency by a convergent construction strategy from 1-hexadecene and d-galactose. The key transformations include Sonogashira coupling, Sharpless asymmetric epoxidation, and Et2AlCl-catalyzed cyclization of an epoxytrichloroacetimidate to generate protected dihydrooxazine 21.