123334-95-2

Upstream product

• 1193-82-4 racemic methyl phenyl sulfoxide 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 123283-69-2 {(1,2,5,6-η)-cycloocta-1,5-diene}{P,O-diphenyl(phenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate 
• 123283-67-0 {(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl(phenylsulphinylmethyl)phosphine}rhodium(I) trifluoromethanesulphonate 
• 123307-15-3 {(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl(phenylsulphinylmethyl)phosphine}rhodium(I) tetrafluorobotate 
• 1309230-98-5 [RhCl[Ph2P(CH2)S(O)Ph-κP](bis(diphenylphosphino)ethane)] 
• 1309231-56-8 [Rh[Ph2P(CH2)S(O)Ph-κP,κO](cycloocta-1,5-diene)][BF4] 
• 1309230-52-1 [Rh[Ph2PCHS(O)Ph-κP,κO](cycloocta-1,5-diene)] 
• 1309230-85-0 [RhCl[Ph2P(CH2)S(O)Ph-κP](cycloocta-1,5-diene)] 

Relevant academic research and scientific papers

Phosphinosulphoxide rhodium complexes. Synthesis, crystal structure, and catalytic chemistry of -hepta-2,5-diene>rhodium(I)trifluoromethanesulphonate and asymmetric analogues

α-Phosphinosulphoxides are readly accessible by the reaction of α-lithioalkylsulphoxides with Ph2PCl, and are stable towards internal oxygen transfer when pure.The compound Ph2PCH2S(O)Ph thus prepared was shown to form a cationic rhodium bicyclohep