1233340-90-3Relevant academic research and scientific papers
Platinum-catalyzed cycloisomerization of 1,4-enynes via activation of a sp3-hybridized C-H bond
Vasu, Dhananjayan,Das, Arindam,Liu, Rai-Shung
supporting information; experimental part, p. 4115 - 4117 (2010/08/22)
We report the cycloisomerization of 1-alkenyl-1-alkynylcyclopropanes to cyclooctatriene products catalyzed by PtCl2/CO in hot xylene. In contrast to the reported enyne cycloisomerization, this 1,4-enyne cycloisomerization proceeds via an atypical addition of the allyl carbon to the alkyne in a 6-endo-dig cyclization.
