1233342-74-9Relevant academic research and scientific papers
Diastereoselective and highly enantioselective henry reactions using C 1-symmetrical copper(II) complexes
Chougnet, Antoinette,Zhang, Guoqi,Liu, Kegang,Haeussinger, Daniel,Kaegi, Andreas,Allmendinger, Thomas,Woggon, Wolf-D.
experimental part, p. 1797 - 1806 (2011/09/13)
Catalytic Henry reactions of aliphatic aldehydes and prochiral nitro compounds were investigated using copper(II) complexes of 14 C 1-symmetrical ligands derived from (1R,2R)(-)-diaminocyclohexane. β-Nitro alcohols with syn:anti ratios of up to 5.7 and excellent ee values for both diastereosimers were obtained. Copyright
Enantioselective henry addition of methyl 4-nitrobutyrate to aldehydes. Chiral building blocks for 2-pyrrolidinones and other derivatives
Blay, Gonzalo,Hernandez-Olmos, Victor,Pedro, Jose R.
supporting information; experimental part, p. 3058 - 3061 (2010/08/19)
A catalytic highly enantioselective Henry addition of methyl 4-nitrobutyrate to aldehydes using a Cu(II)-amino pyridine complex as catalyst is described. The products resulting from this reaction constitute a new, highly versatile family of chiral buildin
