1233347-95-9Relevant academic research and scientific papers
On the [3 + 2] annulation of cyclic allylsilanes with N -phenyltriazolinedione: An enantio- and diastereoselective synthesis of cis -1,3-diaminocyclitols
Dey, Raudra T.,Sarkar, Tarun K.
supporting information; scheme or table, p. 4521 - 4529 (2010/10/03)
(Figure presented) Improved conditions were found to trigger [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione (PTAD); the products from this reaction were readily tailored into cis-1,3-diaminocyclitols in highly enantioenriched form with full stereochemical control of up to four contiguous stereogenic centers.
