123344-06-9Relevant academic research and scientific papers
"Carbocation watching" in solvolysis reactions
Schaller, Heike F.,Mayr, Herbert
, p. 3958 - 3961 (2008)
(Figure Presented) The missing link between conventional SN1 reactions and the chemistry of stable carbocations has been found. When water is added to the colorless solution of the covalent compound Ar2CH-OAc (Ar = morpholinophenyl)
Ambident reactivities of formaldehyde n,n-dialkylhydrazones
Maji, Biplab,Troshin, Konstantin,Mayr, Herbert
, p. 11900 - 11904 (2013/11/19)
What can attack at carbon? With a nucleophilicity N≈7 for attack at the azomethine carbon, formaldehyde hydrazones can undergo noncatalyzed reactions at room temperature with electrophiles that have a reactivity parameter E that is greater than -12. Copyright
Nucleophilic reactivities of tertiary alkylamines
Ammer, Johannes,Baidya, Mahiuddin,Kobayashi, Shinjiro,Mayr, Herbert
, p. 1029 - 1035 (2011/07/09)
The kinetics of the reactions of tertiary amines, triethylamine (1a), N-methylpyrrolidine (1b), N-methylpiperidine (1c), and N-methylmorpholine (1d) with benzhydrylium ions (Ar2CH+) have been studied in acetonitrile and dichlorometha
