123359-08-0Relevant academic research and scientific papers
3-silicon based containing 1,2,3,5-tetrasubstituted benzene and synthetic method thereof
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Paragraph 0019; 0020, (2018/12/13)
The invention discloses a 3-silicon based containing 1,2,3,5-tetrasubstituted benzene synthetized by utilizing a simple aryne precursor containing a silicon group at 3-position and a synthetic methodthereof. A structure is shown as the description. The sy
Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides
Li, Yuanyuan,Qiu, Dachuan,Gu, Rongrong,Wang, Junli,Shi, Jiarong,Li, Yang
supporting information, p. 10814 - 10817 (2016/09/12)
An aryne 1,2,3-trisubstitution with aryl allyl sulfoxides is accomplished, featuring an incorporation of C-S, C-O, and C-C bonds on the consecutive positions of a benzene ring. The reaction condition is mild with broad substrate scope. Preliminary mechani
Temperature, Solvent, and Substituent Effects on the Singlet Oxidations of Allylic Phenyl Sulfoxides, Sulfones, and Sulfides
Clennan, Edward L.,Chen, Xiangning
, p. 8212 - 8218 (2007/10/02)
The reaction of singlet oxygen with a series of allylic sulfoxides, sulfones, and sulfides have been examined as a function of extent of reaction, temperature, and solvent.Hydroperoxy groups but not alkyl, hydrogen, or hydroxyl on chiral carbons β to sulfide sulfur induce diastereoselective sulfoxide formations.Evidence is presented that suggests that the oxidation at sulfur occurs with anchimeric assistance from the hydroperoxy group via a favorable sulfurane-like transition state.
