1233938-63-0Relevant academic research and scientific papers
Remarkably variable reaction modes of frustrated Lewis pairs with non-conjugated terminal diacetylenes
Chen, Chao,Froehlich, Roland,Kehr, Gerald,Erker, Gerhard
supporting information; experimental part, p. 3580 - 3582 (2010/08/07)
The frustrated Lewis pair P(o-tolyl)3/B(C6F 5)3 reacts with 1,7-octadiyne by acetylene C-C coupling to yield the zwitterionic product 2a. In contrast, the P(o-tolyl) 3/B(C6F5)3 Lewis pair reacts with 1,6-heptadiyne by a sequence involving 1,1-carboboration of a terminal acetylene to eventually yield the heterocyclic product 4.
