123411-94-9Relevant academic research and scientific papers
Lewis acid-mediated reaction with silyl ketene acetals and allylstannane of the aluminum acetals generated by DIBALH reduction of α-amino acid esters
Kiyooka,Suzuki,Shirouchi,Kaneko,Tanimori
, p. 5729 - 5732 (2007/10/02)
The intermediates generated by DIBALH reduction of α-amino acid esters undergo condensation without racemization with silyl ketene acetals and allylstannane in the presence of Lewis acid to afford the corresponding β-hydroxy esters and homoallylic alcohol
LEWIS ACID-PROMOTED DIRECT SUBSTITUTION OF 4-METHOXY- AND 4-PHENYLTHIO-2-OXAZOLIDINONES BY ALKYL CUPRATES. FACILE PREPARATION OF (3S,4S)-STATINE AND (3S,4S)-CYCLOHEXYLSTATINE.
Ishibuchi, Seigo,Ikematsu, Yumi,Ishizuka, Tadao,Kunieda, Takehisa
, p. 3523 - 3526 (2007/10/02)
Treatment of 4-methoxy- and 4-phenylthio-2-oxazolidinones with a combination of cuprates and BF3 results in smooth formation of 4-alkyl- and 4-aryl derivatives in high yield.By this method, the titled compounds of biological interest are readily synthesiz
