1234293-57-2Relevant academic research and scientific papers
Asymmetric total synthesis of (+)-6-epi-castanospermine by the stereoselective formation of a syn,anti acetylenic 2-amino-1,3-diol stereotriad
Louvei, Julien,Botuha, Candice,Chemla, Fabrice,Demont, Emmanuel,Ferreira, Franck,Perez-Luna, Alejandro
, p. 2921 - 2926 (2010)
The asymmetric total synthesis of (+)-6-epi-castanospermine (1) is described herein. In this synthesis the diastereoselective addition of a racemic allenylzinc reagent to an enantiopure α-alkoxy-fert-butylsulfinylimine is the key step and is followed by t
