123432-02-0

Basic information

• Product Name: methyl 2-(6-oxo-1-heptynyl)benzoate
• Synonyms: methyl 2-(6-oxo-1-heptynyl)benzoate
• CAS NO: 123432-02-0
• Molecular Weight: 244.29
• Mol File: 123432-02-0.mol

Chemical Properties

• CAS DataBase Reference: methyl 2-(6-oxo-1-heptynyl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(6-oxo-1-heptynyl)benzoate(123432-02-0)
• EPA Substance Registry System: methyl 2-(6-oxo-1-heptynyl)benzoate(123432-02-0)

Safety Data

• Hazardous Substances Data: 123432-02-0(Hazardous Substances Data)

Upstream product

• 610-94-6 2-bromobenzoic acid methyl ester 
• 74066-96-9 2-methyl-2-(pent-4-yn-1-yl)-1,3-dioxolane 
• 123432-01-9 methyl 2-<5-(2-methyl-1,3-dioxan-2-yl)-1-heptynyl>benzoate 

Downstream Products

• 123432-03-1 o-(6-methyl-6-hepten-1-ynyl)-α-diazoacetophenone 
• 133446-31-8 methyl 2-(6-methyl-6-hepten-1-ynyl)benzoate 
• 133446-34-1 methyl o-(6-methyl-6,8-nonadien-1-ynyl)benzoate 

Relevant articles and documents

CYCLOALKENONE FORMATION BY THE INTRAMOLECULAR ADDITION OF A α-DIAZOKETONE TO AN ACETYLENIC PI-BOND

Treatment of several ortho alkynyl substituted α-diazoacetophenone derivatives with rhodium (II) acetate results in intramolecular addition to the acetylenic pi-bond to give a transient cyclopropene which spontaneously rearranges to a vynil carbene interm

Rhodium(II)-Catalyzed Cyclization Reactions of Alkynyl-Substituted α-Diazo Ketones

Treatment of several o-alkynyl-substituted α-diazoacetophenone derivatives with rhodium(II) carboxylates results in the formation of substituted indenones.The simplest mechanism accounting for the results involves addition of a rhodium-stabilized carbenoi