123464-35-7Relevant academic research and scientific papers
Preparation of Polyfunctional Nitro Olefins and Nitroalkanes Using the Copper-Zinc Reagents RCu(CN)ZnI
Jubert, Carole,Knochel, Paul
, p. 5431 - 5438 (2007/10/02)
The addition of the copper-zinc reagents RCu(CN)ZnX to a variety of nitro olefins produces polyfunctional nitroalkanes in high yields.The intermediate zinc or copper nitronates can be directly submitted to a Nef reaction (O3, -78 deg C) and converted to p
Preparation and Reaction of Zinc and Copper Organometallics Bearing Acidic Hydrogens
Knoess, H. Peter,Furlong, Michael T.,Rozema, Michael J.,Knochel, Paul
, p. 5974 - 5978 (2007/10/02)
Organozinc and copper ragents bearing unprotected primary or secondary amines or amides or a terminal acetylenic proton were prepared and reacted with various electrophiles in good yields.
The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins
Retherford, Carole,Yeh, Ming Chang P.,Schipor, Ioana,Chen, Huai Gu,Knochel, Paul
, p. 5200 - 5202 (2007/10/02)
The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted int
