123464-48-2Relevant academic research and scientific papers
Preparation of Polyfunctional Nitro Olefins and Nitroalkanes Using the Copper-Zinc Reagents RCu(CN)ZnI
Jubert, Carole,Knochel, Paul
, p. 5431 - 5438 (2007/10/02)
The addition of the copper-zinc reagents RCu(CN)ZnX to a variety of nitro olefins produces polyfunctional nitroalkanes in high yields.The intermediate zinc or copper nitronates can be directly submitted to a Nef reaction (O3, -78 deg C) and converted to p
The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins
Retherford, Carole,Yeh, Ming Chang P.,Schipor, Ioana,Chen, Huai Gu,Knochel, Paul
, p. 5200 - 5202 (2007/10/02)
The addition of the highly functionalized zinc and copper organometallics FG-RCu(CN)ZnI to nitro olefins furnishes polyfunctional nitroalkanes in good to excellent yields; with α-substituted nitro olefins, the Michael adducts can be directly converted int
