1234935-52-4Relevant academic research and scientific papers
Regioselective silylzincation of phenylallene derivatives
Yonehara, Mitsuhiro,Nakamura, Shinji,Muranaka, Atsuya,Uchiyama, Masanobu
, p. 452 - 455 (2010)
This paper deals with our new approach for regio-controlled synthesis of exo/endo-vinylsilanes through silylzincation as a key reaction, using newly developed silylzinc reagents. In this system, by choosing appropriate zinc reagents, either exo-vinylsilane or endo-vinylsilane can be synthesized with good regioselectivity, using the same phenylallene substrates. (Chemical equation presented).
