123501-10-0Relevant academic research and scientific papers
New Cyclopentadienones from Sterically Demanding Inner Acetylenes and Dicobalt-octacarbonyl
Dehmlow, Eckehard V.,Winterfeldt, Andreas
, p. 455 - 458 (2007/10/02)
Acetylenes carrying one bulky substituent can be transformed into symmetrically or asymmetrically substituted ccylopentadienones 2 or 3 when they are heated with Co2(CO)8 and carbon monoxide.Intramolecular cyclizations yielding compounds 5 are also possible. - Keywords: Alkyne-Carbon Monoxide Reaction, Metal Carbonyl Catalysis, Cyclopentadienones, Cycloalkanocyclopentadienones
