123507-31-3Relevant articles and documents
Complete Control of the Rearrangement Modes of Enolates of α-Allyloxy Ketones: Reversal from the -Claisen to the -Wittig Pathway by the Use of the Metalated N,N-Dimethylhydrazones
Luengo, Juan I.,Koreeda, Masato
, p. 5415 - 5417 (1989)
It has been shown that the predilection for the -Claisen rearrangement pathway of enolates of α-allyloxy ketones is cleanly overridden by the -Wittig rearrangement route with the use of carboanions of their corresponding N,N-dimethylhydrazones.S