123518-02-5Relevant articles and documents
CYCLIZATION OF NITRILES. XXX. SYNTHESIS, STRUCTURE, AND PROPERTIES OF 6-AMINO-4-ARYL(HETEROARYL)-3,5-DICYANO-2(1H)-PYRIDINETHIONES
Sharanin, Yu. A.,Promomenkov, V. N.,Shestopalov, A. M.,Nestorov, V. N.,Malenchuk, S. N.,et al.
, p. 560 - 565 (2007/10/02)
The reactions of arylmethylenecyanothioacetamides with malononitrile and of arylmethylenemalononitriles with cyanothioacetamide take place regioselectively with the formation of 6-amino-4-aryl-3,5-dicyano-2(1H)-pyridinethiones and not 5-arylmethylene-4,6-diamino-3-cyanopyridine-2-thiones.The 6-amino-4-aryl-3,5-dicyano-2(1H)-pyridinethiones are formed by the recyclization of the 4-aryl-2,6-diamino-3,5-dicyano-4H-thiopyranes.