1235294-89-9Relevant academic research and scientific papers
Synthesis of nitrodienes, nitrostyrenes, and nitrobiaryls through palladium-catalyzed couplings of β-nitrovinyl and o-nitroaryl thioethers
Creech, Gardner S.,Kwon, Ohyun
, p. 2670 - 2674 (2013/07/11)
A highly efficient, base-free, mild protocol for the palladium-catalyzed, copper-activated desulfitative couplings of vinyl and aryl β- nitrothioethers generates a wide variety of conjugated nitroorganics. Orthogonality to traditional Suzuki-Miyaura coupling is demonstrated, as well as synthetic utility, through reductive Cadogan cyclization, for the formation of indoles, carbazoles, and pyrroles.
Tandem 6π-electrocyclization and cycloaddition of nitrodienes to yield multicyclic nitroso acetals
Creech, Gardner S.,Kwon, Ohyun
supporting information; experimental part, p. 8876 - 8877 (2010/08/21)
Upon heating, nitrodienes rearrange through 6π-electrocyclization to form nitronate intermediates, which can be captured through tandem [3 + 2] dipolar cycloadditions to form highly functionalized nitroso acetals. The one-pot, two-step domino process is h
