1235319-92-2Relevant articles and documents
Square-planar 2-toluenido(triphenylphosphane)nickel(II) complexes containing bidentate N,O ligands: An example of planar chirality
Beckmann, Udo,Haegele, Gerhard,Frank, Walter
, p. 1670 - 1678 (2010)
Nickel(II) complexes comprising electronically delocalised N,O-chelating ligands are active catalysts in the copolymerisation of carbon monoxide and ethene. Elucidating the mechanism of catalysis presupposes the basic understanding of the intramolecular flexibility of such transition metal complexes. Several nickel(II) complexes with or without planar chirality were synthesised and characterised by NMR spectroscopic techniques and X-ray diffraction.