123541-41-3Relevant academic research and scientific papers
Preparation of benzene and Its Reactivity toward Carbonyl Compounds
Hatzigrigoriou, Evangelia,Varvoglis, Anastasios,Bakola-Christianopoulou, Maria
, p. 315 - 318 (2007/10/02)
The title compound is prepared and used for the direct α-((10-camphorsulfonyl)oxylation) of various ketones and carbonyl compounds with an active methylene group.Its reaction with 2-butanone and 4-methyl-2-pentanone yields predominantly the corresponding 1-sulfonyloxy derivatives.The stereoselectivity of the reaction is studied by using benzoylacetone, ethyl benzoylacetate, and propiophenone.In some reactions 10-camphorsulfonyl peroxide is formed as a byproduct.
