123552-85-2Relevant academic research and scientific papers
Lewis acid mediated reactions of n-arylsulfonimidoyl chlorides with alkenes. some steric effects of alkene substitution
Harmata, Michael,Kahraman, Mehmet
, p. 6845 - 6851 (1998)
The Lewis acid-mediated reaction of AT-phenyl-S-(4-methylphenyl)sulfonimidoyl chloride with alkenes was explored in order to determine the effect of alkene substitution on the stereochemical outcome of the reaction. With monosubstituted alkenes, benzothia
KINETICS AND MECHANISMS OF THE ACID-CATALYSED HYDROLYSES OF 4-NITROPHENYL-N-AROYL-ARENEIMINOSULPHONATES
Kutuk, Halil,Tillett, John
, p. 217 - 224 (2007/10/02)
The acid catalysed hydrolyses of N-acetyl and a series of N-aroylsulphonimidic esters have been studied in aqueous 40percent (v/v) dioxane solutions of mineral acids.At low acidity all the esters studied are considered to hydrolyse by an A-2 mechanism.At
Lewis Acid Mediated Reaction of N-Phenyl-S-(4-methylphenyl)sulfoximidoyl Chloride with Alkenes
Harmata, Michael,Claassen, R. J.,Barnes, Charles L.
, p. 5059 - 5062 (2007/10/02)
The reaction of N-phenyl-S-(4-methylphenyl)sulfoximidoyl chloride (1) with alkenes in the presence of aluminum chloride leads to 2,1-benzothiazines in good yield.The reaction is regioselective, sometimes highly stereoselective, and is stereospecific with
Synthesis, deprotonation, and alkylation of S-allyl sulfoximines
Harmata,Claassen II
, p. 6497 - 6500 (2007/10/02)
N-Phenyl-S-(4-methylphenyl)-sulfoximidoyl chloride 1 reacts with allyltrimethylsilane in the presence of aluminum chloride to give benzothiazine 4 in fair yield along with a small amount of S-allyl sulfoximine 3a. On the other hand, 1 reacts with allyltributyltin to give the S-allyl sulfoximine 3a almost exclusively. This latter reaction appears to be general. The sulfoximine 3a is thermally stable and can be deprotonated smoothly with n-BuLi. The anion reacts regioselectively but not stereoselectively with simple alkylating agents. Reactions of the anion with selected aldehydes and enones proceeds with some regiocontrol and, with some exceptions, little stereocontrol.
A NEW SULFOXIMINE SYNTHESIS
Harmata, Michael
, p. 437 - 440 (2007/10/02)
Selected sulfonimidoyl halides react with ethylaluminum dichloride to give S-ethyl sulfoximines in good yields.
