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4-Methyl-N-phenylbenzene Sulfonimidoyl Chloride is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

123552-85-2

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123552-85-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 123552-85-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,5,5 and 2 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 123552-85:
(8*1)+(7*2)+(6*3)+(5*5)+(4*5)+(3*2)+(2*8)+(1*5)=112
112 % 10 = 2
So 123552-85-2 is a valid CAS Registry Number.

123552-85-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name N-phenyl-S-(4-methylphenyl)sulfoximidoyl chloride

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:123552-85-2 SDS

123552-85-2Relevant academic research and scientific papers

Lewis acid mediated reactions of n-arylsulfonimidoyl chlorides with alkenes. some steric effects of alkene substitution

Harmata, Michael,Kahraman, Mehmet

, p. 6845 - 6851 (1998)

The Lewis acid-mediated reaction of AT-phenyl-S-(4-methylphenyl)sulfonimidoyl chloride with alkenes was explored in order to determine the effect of alkene substitution on the stereochemical outcome of the reaction. With monosubstituted alkenes, benzothia

KINETICS AND MECHANISMS OF THE ACID-CATALYSED HYDROLYSES OF 4-NITROPHENYL-N-AROYL-ARENEIMINOSULPHONATES

Kutuk, Halil,Tillett, John

, p. 217 - 224 (2007/10/02)

The acid catalysed hydrolyses of N-acetyl and a series of N-aroylsulphonimidic esters have been studied in aqueous 40percent (v/v) dioxane solutions of mineral acids.At low acidity all the esters studied are considered to hydrolyse by an A-2 mechanism.At

Lewis Acid Mediated Reaction of N-Phenyl-S-(4-methylphenyl)sulfoximidoyl Chloride with Alkenes

Harmata, Michael,Claassen, R. J.,Barnes, Charles L.

, p. 5059 - 5062 (2007/10/02)

The reaction of N-phenyl-S-(4-methylphenyl)sulfoximidoyl chloride (1) with alkenes in the presence of aluminum chloride leads to 2,1-benzothiazines in good yield.The reaction is regioselective, sometimes highly stereoselective, and is stereospecific with

Synthesis, deprotonation, and alkylation of S-allyl sulfoximines

Harmata,Claassen II

, p. 6497 - 6500 (2007/10/02)

N-Phenyl-S-(4-methylphenyl)-sulfoximidoyl chloride 1 reacts with allyltrimethylsilane in the presence of aluminum chloride to give benzothiazine 4 in fair yield along with a small amount of S-allyl sulfoximine 3a. On the other hand, 1 reacts with allyltributyltin to give the S-allyl sulfoximine 3a almost exclusively. This latter reaction appears to be general. The sulfoximine 3a is thermally stable and can be deprotonated smoothly with n-BuLi. The anion reacts regioselectively but not stereoselectively with simple alkylating agents. Reactions of the anion with selected aldehydes and enones proceeds with some regiocontrol and, with some exceptions, little stereocontrol.

A NEW SULFOXIMINE SYNTHESIS

Harmata, Michael

, p. 437 - 440 (2007/10/02)

Selected sulfonimidoyl halides react with ethylaluminum dichloride to give S-ethyl sulfoximines in good yields.

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