1235568-91-8Relevant academic research and scientific papers
New carbazole-based host material for low-voltage and highly efficient red phosphorescent organic light-emitting diodes
Kwak, Jeonghun,Lyu, Yi-Yeol,Lee, Hyunkoo,Choi, Bonggoo,Char, Kookheon,Lee, Changhee
, p. 6351 - 6355 (2012)
A new carbazole-based host material for red emitters, BBTC, was designed, synthesized and characterized with the phosphorescent organic light-emitting diodes (PHOLEDs). With the molecular design strategy of maintaining the large triplet energy and a good hole transporting ability of carbazole while increasing the morphological and electrochemical stability, the C3 and C6 positions of carbazole are blocked with biphenyl groups and the C9 position is terminated with a terphenyl group. Red PHOLEDs employing a conventional dopant material, bis(1-phenylisoquinoline)(acetylacetonate)iridium(iii) ((piq) 2Ir(acac)), in the emissive layer showed nearly 100% internal quantum efficiency (corresponding to the external quantum efficiency of 19.3%) with reduced efficiency roll-off. We attribute these results to the good electron-hole balance resulting from the good hole mobility of BBTC and low hole injection barrier from the hole transport layer to BBTC host in the emission layer. In addition, owing to its good hole transporting property, it can be utilized as a hole transport layer in organic light-emitting devices enabling low voltage operation of the devices. The Royal Society of Chemistry 2012.
Carbazole-based compound and organo-electroluminescent device using the same
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, (2017/01/09)
A carbazole compound represented by Formula 1: wherein X1, X2 and X3 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C6-C30 aryl group, a substituted or unsubstituted C6-C30 arylalkyl group, a substituted or unsubstituted C2-C30 heteroaryl group, a substituted or unsubstituted C3-C20 cycloalkyl group and a substituted or unsubstituted C5-C30 heterocycloalkyl group; and l, m and n are each independently an integer from 0 to 5.
