123559-05-7

Basic information

• Product Name: 3,3-bismethylthio-1-methyl-1-phenylprop-2-en-1-ol
• Synonyms: 3,3-bismethylthio-1-methyl-1-phenylprop-2-en-1-ol
• CAS NO: 123559-05-7
• Molecular Weight: 240.39
• Mol File: 123559-05-7.mol

Chemical Properties

• CAS DataBase Reference: 3,3-bismethylthio-1-methyl-1-phenylprop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-bismethylthio-1-methyl-1-phenylprop-2-en-1-ol(123559-05-7)
• EPA Substance Registry System: 3,3-bismethylthio-1-methyl-1-phenylprop-2-en-1-ol(123559-05-7)

Safety Data

• Hazardous Substances Data: 123559-05-7(Hazardous Substances Data)

Upstream product

• 13636-88-9 3,3-bis(methylthio)-1-phenylprop-2-en-1-one 
• 74-88-4 methyl iodide 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 77149-41-8 1,1-bis(methylthio)-3-phenyl-1,3-butadiene 
• 99142-97-9 S-methyl β-methylthiocinnamate 
• 3461-50-5 methyl trans-3-methylcinnamate 

Relevant articles and documents

Vilsmeier-Haack reactions of α-hydroxyketenedithioacetals: A facile synthesis of substituted pyridines

The reaction of α-hydroxyketenedithioacetals, generated by the 1,2-addition of methyl Grignard reagent to α-oxoketenedithioacetals, with the Vilsmeier reagent was investigated. The reaction proceeds with acid-catalysed dehydration to afford sulphur substituted 1,3-butadienes, which undergo subsequent iminoalkylations. The intermediate iminium salts formed were successfully transformed into 2-methylsulfanyl substituted 4-aryl pyridines, in the presence of ammonium acetate

Reactions of α-hydroxyketene dithioacetals with Lawesson's reagent: An efficient method for the synthesis of α,β-unsaturated dithioesters

The α-hydroxyketene dithioacetals 2 and 5, obtained from α-oxoketene dithioacetals by the 1,2-reduction or the 1,2-addition of carbon nucleophiles, on treatment with Lawesson's reagent afforded α,β-unsaturated dithioesters 3 and 6 in good yields. Georg Th

STUDIES ON DIELS-ALDER CYCLOADDITIONS OF VINYLKETENE DITHIOACETALS

The Diels-Alder cycloadditions of the acyclic and cyclic vinylketene dithioacetals 4 prepared from the corresponding oxoketene dithioacetals 2, either by 1,2-addition of methylmagnesium iodide and subsequent dehydration or by Wittig reaction, were studied

Polarized Ketene Dithioacetals. Part 42. Studies on the Reactions of Alkyl and Aryl Grignard Reagents with α-Oxoketene Dithioacetals

The oxoketene dithioacetals (2a-k) derived from a variety of cyclic and acyclic active methylene ketones undergo 1,2-addition with methylmagnesium iodide to give the alcohol acetals (3a-k) which, on subsequent boron trifluoride-ether catalysed methanolysi