1235818-76-4Relevant academic research and scientific papers
Biomimetic synthesis of polycyclic polyprenylated acylphloroglucinol natural products isolated from hypericum papuanum
George, Jonathan H.,Hesse, Micha D.,Baldwin, Jack E.,Adlington, Robert M.
, p. 3532 - 3535 (2010)
(Equation Presented). Biomimetic syntheses of three polycylic polyprenylated acylphloroglucinol natural products isolated from Hypericum papuanum, ialibinone A, ialibinone B, and hyperguinone B, have been accomplished by selective oxidative cyclizations o
Expedient synthesis of ialibinones A and B by manganese(III)-mediated oxidative free radical cyclisation
Simpkins, Nigel S.,Weller, Michael D.
experimental part, p. 4823 - 4826 (2010/10/02)
The tricyclic natural products ialibinone A and ialibinone B were prepared as a 41:59 mixture in four steps starting from phloroglucinol. The synthetic sequence involved (i) acylation of phloroglucinol under Friedel-Crafts conditions, (ii) double prenylat
