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1236115-61-9

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1236115-61-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1236115-61-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,3,6,1,1 and 5 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1236115-61:
(9*1)+(8*2)+(7*3)+(6*6)+(5*1)+(4*1)+(3*5)+(2*6)+(1*1)=119
119 % 10 = 9
So 1236115-61-9 is a valid CAS Registry Number.

1236115-61-9Downstream Products

1236115-61-9Relevant articles and documents

Pyrrole synthesis via allylic sp3 C-H activation of enamines followed by intermolecular coupling with unactivated alkynes

Rakshit, Souvik,Patureau, Frederic W.,Glorius, Frank

supporting information; experimental part, p. 9585 - 9587 (2010/09/10)

A conceptually novel pyrrole synthesis is reported, efficiently merging enamines and (unactivated) alkynes under oxidative conditions. In an intermolecular Rh catalyzed process, the challenging allylic sp3 C-H activation of the enamine substrates is followed by the cyclization with the alkyne (R3 = CO2R). Alternatively, in some cases (R 3 = CN), the enamine can be utilized for a vinylic sp2 C-H activation. A total of 17 examples with yields above 60% is presented, together with the results of an initial mechanistic investigation.

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