123622-06-0

Basic information

• Product Name: 1-(2-Methyl-1-phenoxy-propyl)-1H-benzotriazole
• Synonyms: 1-(2-Methyl-1-phenoxy-propyl)-1H-benzotriazole
• CAS NO: 123622-06-0
• Molecular Weight: 267.33
• Mol File: 123622-06-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2-Methyl-1-phenoxy-propyl)-1H-benzotriazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-Methyl-1-phenoxy-propyl)-1H-benzotriazole(123622-06-0)
• EPA Substance Registry System: 1-(2-Methyl-1-phenoxy-propyl)-1H-benzotriazole(123622-06-0)

Safety Data

• Hazardous Substances Data: 123622-06-0(Hazardous Substances Data)

Upstream product

• 139-02-6 sodium phenoxide 
• 111098-59-0 1-(benzotriazol-1-yl)-1-chloro-2-methylpropane 

Downstream Products

• 62338-26-5 (1,2-dimethylpropoxy)benzene 

Relevant articles and documents

Reactions of 1-(α-Alkoxyalkyl)- and 1-(α-(Aryloxy)alkyl)benzotriazoles with the Grignard Reagents. A New and Versatile Method for the Preparation of Ethers

1-(α-Alkoxyalkyl)benzotriazoles deriving from aldehydes (other than formaldehyde), or from ketones, react with Grignard reagents at 110 deg C to provide a high-yielding, general synthesis of dialkyl and aryl ethers.Under similar conditions, 1-(alkoxymethyl)- and 1-((aryloxy)methyl)benzotriazoles give, by a different cleavage pattern of the N-C-O grouping, 1-alkylbenzotriazoles and N,N'-dialkyl-o-phenylenediamines.The 1-(α-alkoxyalkyl)benzotriazoles are easily prepared: (a) by condensation of benzotriazole, an aldehyde, and an alcohol under water-removing conditions; (b) by condensation of a 1-(α-chloroalkyl)benzotriazole with a sodium or potassium alkoxide or aryloxide; and (c) by condensatioon of an acetal or a ketal with benzotriazole.All the 1-(α-alkoxyalkyl)benzotriazoles and dialkyl or alkyl aryl ethers obtained were fully characterized by their 1H and 13C NMR spectra.