123628-93-3Relevant academic research and scientific papers
The Stereochemistry of Organometallic Compounds. XXXIV. Regioselection in the Hydroformylation of Silylalkenes
Doyle, M. Michael,Jackson, W. Roy,Perlmutter, Patrick
, p. 1907 - 1918 (2007/10/02)
The regiochemistry of hydroformylation of alkenes can be controlled by use of bulky silyl groups attached to the alkene.Use of the t-butyldiphenylsilyl group leads to almost total regiocontrol and the method has been applied to the synthesis of aldols.
REGIOSELECTION IN THE HYDROFORMYLATION OF t-BUTYLDIPHENYLSILYLALKENES: A NEW APPROACH TO ALDOL SYNTHESIS
Doyle, M. Michael,Jackson, W. Roy,Perlmutter, Patrick
, p. 233 - 234 (2007/10/02)
Hydroformylation of (Z)-alkenes bearing a t-butyldiphenylsilyl group (TBDPS) yields, almost exclusively, β-silylaldehydes and the methodology has been used to establish a new aldol synthesis.
