123703-33-3Relevant academic research and scientific papers
HIGHLY DIASTEREOSELECTIVE SYNTHESIS OF CYCLIC NITRONIC ESTERS FROM 1-(4-MORPHOLINYL)-1-PHENYLPROPENE WITH NITROOLEFINS
Felluga, F.,Nitti, P.,Pitacco, G.,Valentin, E.
, p. 2099 - 2108 (2007/10/02)
1,2-Oxazine N-oxide derivatives could be obtained as pure isomers from the title reagents.In methanol, they opened into the corresponding Michael-type adducts, as single double bond diastereoisomers.Hydrolyses of both the systems were also highly diastereoselective, leading to γ-diketones in the former case and to γ-nitroketones in the latter.
