1237493-25-2Relevant academic research and scientific papers
Access to well-defined Ruthenium(I) and Osmium(I) metalloradicals
Takaoka, Ayumi,Gerber, Laura C. H.,Peters, Jonas C.
, p. 4088 - 4091 (2010)
Figure Presented Radically complex: Well-defined mononuclear RuI and OsI complexes (see scheme) have metalloradical character, as indicated by EPR spectroscopy and DFT calculations. The RuI and OsI metalloradicals exhibit both one-electron and two-electron redox reactivity. The latter process affords unusual imido complexes with substantial radical character on the {ArN} moiety.
