123751-07-5

Upstream product

• 123808-74-2 (rac)-2-(dibenzylamino)-3-phenylpropionaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 
• 123054-12-6 (2S)-N,N-dibenzylphenylalaninal 

Downstream Products

• 123751-17-7 (E)-4-(Dibenzylamino)-5-phenyl-2-penten-1-ol 
• 123751-13-3 (Z)-(S)-4-Dibenzylamino-5-phenyl-pent-2-en-1-ol 
• 138041-36-8 (Z)-(3S,6S)-6-Dibenzylamino-3-hydroxy-2,2-dimethyl-7-phenyl-hept-4-enoic acid methyl ester 
• 138041-50-6 (Z)-(3R,6S)-6-Dibenzylamino-3-hydroxy-2,2-dimethyl-7-phenyl-hept-4-enoic acid methyl ester 
• 138041-49-3 (Z)-(3S,6S)-6-Dibenzylamino-3-hydroxy-7-phenyl-hept-4-enoic acid methyl ester 
• 138041-35-7 (Z)-(3R,6S)-6-Dibenzylamino-3-hydroxy-7-phenyl-hept-4-enoic acid methyl ester 
• 138059-58-2 (Z)-(1R,4S)-4-Dibenzylamino-1,5-diphenyl-pent-2-en-1-ol 
• 138041-34-6 (Z)-(1S,4S)-4-Dibenzylamino-1,5-diphenyl-pent-2-en-1-ol 
• 138041-48-2 (Z)-(2S,5S)-2-Dibenzylamino-1-phenyl-non-3-en-5-ol 
• 138041-33-5 (Z)-(2S,5R)-2-Dibenzylamino-1-phenyl-non-3-en-5-ol 
• 138041-32-4 (Z)-(2R,5S)-5-Dibenzylamino-6-phenyl-hex-3-en-2-ol 
• 138041-47-1 (Z)-(2S,5S)-5-Dibenzylamino-6-phenyl-hex-3-en-2-ol 
• 138041-60-8 (Z)-(S)-4-Dibenzylamino-5-phenyl-pent-2-enal 
• 123751-28-0 (2S*,1'S)-2-<1-(Dibenzylamino)-2-phenylethyl>-3-buten-1-ol 

Relevant academic research and scientific papers

Novel 1,4-Asymmetric Induction in Nucleophilic 1,2-Additions to Chiral γ-Amino Enals

γ-Dibenzylamino enals 3a with the E-configuration derived from amino acids 1 react diastereoselectively with cuprates in an unexpected 1,2-manner, while the analogues 3b with the Z-configuration undergo diastereoselective additions with organolithium reagents.

Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter - Diastereocontrol by Allylic Nitrogen

The stereochemistry of Wittig-Still rearrangements under the influence of an allylic stereogenic center attached by Bn2N or RNBoc groups is studied.Rearrangements are subject to stereocontrol through asymmetric induction.Stannylated allyl ethers 13 with Z double bonds give syn-configuration amino alcohols 15 exclusively (ds >95:99.8:0.2).Stannanes of E configuration 14 lead to 15 less selectively (syn:anti = 46:54 - 92:8).X-ray structural data are provided for amino alcohols syn-15b and for the bis(carbamate) 17.