1237525-06-2Relevant academic research and scientific papers
Asymmetrie synthesis of allylsilanes by the borylation of lithiated carbamates: Formal total synthesis of (-)-decarestrictine D
Binanzer, Michael,Fang, Guang Yu,Aggarwal, Varinder K.
supporting information; experimental part, p. 4264 - 4268 (2010/08/07)
Chemical equation represented The flip side: (-)-Sparteine-complexed lithiated carbamates react with β-silylvinylboranes with inversion of configuration, whereas the diamine-free lithiated carbamates react with retention of configuration, thereby providing enantiocomplementary routes to β-hydroxy allylsilanes (see scheme). The methodology has been applied in a concise formal total synthesis of (-)-decarestrictine D.
