1237745-14-0

Basic information

• Product Name: 5-phenyl-5H-dibenzo[b,f]borepin
• Synonyms: 5-phenyl-5H-dibenzo[b,f]borepin
• CAS NO: 1237745-14-0
• Molecular Weight: 266.15
• Mol File: 1237745-14-0.mol

Chemical Properties

• CAS DataBase Reference: 5-phenyl-5H-dibenzo[b,f]borepin(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenyl-5H-dibenzo[b,f]borepin(1237745-14-0)
• EPA Substance Registry System: 5-phenyl-5H-dibenzo[b,f]borepin(1237745-14-0)

Safety Data

• Hazardous Substances Data: 1237745-14-0(Hazardous Substances Data)

Upstream product

• 1189139-25-0 5,5-dimethyl-5H-dibenzo[b,f]stannepine 
• 873-51-8 phenylborondichloride 
• 56667-12-0 (Z)-2,2'-dibromostilbene 

Relevant articles and documents

BORON-CONTAINING PI-ELECTRON MATERIALS INCORPORATING FORMALLY AROMATIC AND NEUTRAL BOREPIN RINGS

The synthesis, functionalization and characterization of borepin-based extended pi-electron molecules is disclosed. Bulky substituents shielded the vacant boron p-orbitals thus allowing synthetic manipulation and purification under ambient lab conditions.

Synthesis of functionalizable boron-containing π-electron materials that incorporate formally aromatic fused borepin rings

(Figure Presented) Not a natty B-OH: Borepin-based extended π-electron molecules contain bulky substituents that shield the vacant boron p orbitals and allow synthetic manipulation and purification under ambient conditions. These borepin-containing compounds (see picture; Mes* = 1,3,5-tris(tert-butyl) phenyl; B orange, C gray) display reversible cathodic electrochemistry and can be viewed as n-type analogues to bent acene hydrocarbons.