1237789-57-9Relevant articles and documents
Synthesis of fluorinated amphoteric organoborons: Via iodofluorination of alkynyl and alkenyl MIDA boronates
Fan, Wen-Xin,Li, Ji-Lin,Lv, Wen-Xin,Yang, Ling,Li, Qingjiang,Wang, Honggen
, p. 82 - 85 (2019)
The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C-I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.
Ethynyl MIDA boronate: A readily accessible and highly versatile building block for small molecule synthesis
Struble, Justin R.,Lee, Suk Joong,Burke, Martin D.
experimental part, p. 4710 - 4718 (2010/08/06)
Ethynyl N-methyliminodiacetic acid (MIDA) boronate is a very useful building block for small molecule synthesis. This compound can serve as both a bifunctional acetylene equivalent with the capacity for terminus-selective bis-functionalization and a versatile starting material for the preparation of a wide range of other MIDA boronate building blocks.