1238-31-9Relevant academic research and scientific papers
Anionic Fries Rearrangements of Esters of ortho-Iodobenzyl Alcohols: Rapid Routes to Oestrone Methyl Ether and Its 9β Epimer, and Aryl Naphthalide Lignans
Horne, Stephen,Rodrigo, Russell
, p. 164 - 166 (2007/10/02)
A fast, general, low-temperature rearrangement of ortho-iodobenzyl esters, triggered by lithium-iodine exchange, leads to isobenzofurans which are intercepted in situ by inter and intramolecular Diels-Alder (IMDA) reactions to produce a variety of carbocycles including natural lignans and steroids.
Dimethylcarbonat als Methylierungsmittel unter phasen-transfer-katalytischen Bedingungen
Lissel, Manfred,Schmidt, Stefan,Neumann, Beate
, p. 382 - 383 (2007/10/02)
Dimethyl carbonate (as well as diethyl, diallyl, dibenzyl carbonate and ethane-1,2-diyl carbonate) in the presence of potassium carbonate and 18-crown-6 (or Aliqual 336) is a versatile, cheap, and safer reagent for the methylation of a variety of organic substrates.
