123807-91-0Relevant academic research and scientific papers
Semipreparative synthesis, 13C-and 2D-NMR of Pulo'upone
Matikainen, Jorma,Kaltia, Seppo,Hase, Tapio,Kilpelaeinen, Ilkka,Drakenberg, Torbjoern,Annila, Arto
, p. 8007 - 8014 (2007/10/02)
A mmolar scale synthetic route to (±)-piuo'upone, in 9 steps, 3.8 % overall yield, and under non-epimerizing conditions, is reported. A complete assignment of the compound's 1H and 13C NMR shifts is presented.
ASYMMETRIC TOTAL SYNTHESES OF (+)- AND (-)-PULO'UPONE
Sugahara, Tsutomu,Iwata, Takashi,Yamaoka, Miyako,Takano, Seiichi
, p. 1821 - 1824 (2007/10/02)
Asymmetric total syntheses of both enantiomers of marine mollusk metabolite pulo'upone 1 have been achieved by Evans' asymmetric Diels-Alder reaction.
TOTAL SYNTHESIS OF (+/-)-PULO'UPONE
Burke, Steven D.,Piscopio, Anthony D.,Buchanan, John L.
, p. 2757 - 2760 (2007/10/02)
The first total synthesis of the Hawaiian mollusk metabolite pulo'upone (2) has been achieved, wherein a novel retro hetero Diels-Alder/intramolecular Diels-Alder tandem process established the trans-fused hydrindene nucleus.
