123811-22-3Relevant academic research and scientific papers
Sequential Wittig-Oxyanion Accelerated Cope Reactions of 2,2,2-Triphenyl-5-vinyl-1,2λ5-oxaphospholane
Enholm, Eric J.,Satici, Hikmet,Prasad, Girija
, p. 324 - 329 (2007/10/02)
2,2,2-Triphenyl-5-vinyl-1,2λ5-oxaphospholane was prepared and condensed with a variety of aldehydes and ketones in a Wittig reaction to produce 3-hydroxy 1,5-dienes.These compounds were next subjected to an oxyanion accelerated Cope rearrangement.In the two-step process, the carbonyl was replaced with a difunctionalized carbon bearing a vinyl moiety and a three-carbon pendant aldehyde.
