1238191-88-2Relevant academic research and scientific papers
Facile atom-economic synthesis of ammonium diselenophosphinates via three-component reaction of secondary phosphines, elemental selenium, and ammonia
Artemev, Alexander V.,Malysheva, Svetlana F.,Gusarova, Nina K.,Belogorlova, Nataliya A.,Trofimov, Boris A.
, p. 1777 - 1780 (2010)
The three-component reaction between secondary phosphines, R2PH [R=Ph(CH2)2, PhCHMeCH2, PhCH2CHMe, 4-t-BuC6H4(CH2)2, 4-MeOC 6H4(CH2)2, 2-furyl(CH 2)2, 4-pyridyl(CH2)2, 6-Me-3-pyridyl(CH2)2, Ph], elemental selenium, and ammonia proceeds under mild conditions (EtOH-H2O, 53-55 C or EtOH, r.t., 10 min) without the formation of byproducts to give the first representatives of ammonium diselenophosphinates in high yields (up to 96%). Georg Thieme Verlag Stuttgart - New York.
