123837-09-2

Basic information

• Product Name: 2-Bromo-5-methylfuran
• Synonyms: Furan, 2-bromo-5-methyl- (9CI);2-Bromo-5-methylfuran;Furan,2-bromo-5-methyl
• CAS NO: 123837-09-2
• Molecular Formula: C₅H₅BrO
• Molecular Weight: 161
• Product Categories: HALIDE;Furans
• Mol File: 123837-09-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 133 °C
• Flash Point: 34 °C
• Appearance: /
• Density: 1.537
• Vapor Pressure: 10.8mmHg at 25°C
• Refractive Index: 1.505
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 2-Bromo-5-methylfuran(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-5-methylfuran(123837-09-2)
• EPA Substance Registry System: 2-Bromo-5-methylfuran(123837-09-2)

Safety Data

• Hazardous Substances Data: 123837-09-2(Hazardous Substances Data)

Usage

Uses

2-Bromo-5-methylfuran is used as a reagent to synthesize quinuclidine-based ligands, compounds that act as muscarinic agonists.

InChI:InChI=1/C5H5BrO/c1-4-2-3-5(6)7-4/h2-3H,1H3

Upstream product

• 52804-46-3 5-[(tetrahydro-2H-pyran-2-yl)oxy]pent-3-yn-2-one 
• 41718-86-9 5-bromopenta-3,4-dien-2-one 
• 534-22-5 2-methylfuran 
• 106-93-4 ethylene dibromide 

Downstream Products

• 1614249-60-3 (R)-1,3-dimethyl-10-(5-methylfuran-2-yl)-5-phenyl-7,8,9,10-tetrahydropyrimido[4,5-a]indolizine-2,4(1H,3H)-dione 
• 1614249-61-4 (S)-1,3-dimethyl-10-(5-methylfuran-2-yl)-5-phenyl-7,8,9,10-tetrahydropyrimido[4,5-a]indolizine-2,4(1H,3H)-dione 
• 1614249-59-0 1,3-dimethyl-10-(5-methylfuran-2-yl)-5-phenyl-7,8,9,10-tetrahydropyrimido[4,5-a]indolizine-2,4(1H,3H)-dione 
• 1614251-40-9 1,3-dimethyl-10-(5-methylfuran-2-yl)-5-phenyl-7,8-dihydropyrimido[4,5-a]indolizine-2,4(1H,3H)-dione 
• 1417920-35-4 (+)-(3R,1′S,2'S)-N-(1'-hydroxy-1'-phenylpropan-2'-yl)-N-methyl-3-(5-methylfuran-2-yl)hexanamide 
• 1417920-34-3 (+)-(3R,1′S,2'S)-N-(1'-hydroxy-1'-phenylpropan-2'-yl)-N-methyl-3-(5-methylfuran-2-yl)pentanamide 

Relevant articles and documents

Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index

We have developed a gold affinity index and hydrogen bonding basicity index for counterions and have used these indexes to forecast their reactivity in cationic gold catalysis.

Chemistry of pseudomonic acid. Part 16. Aryl and heteroaryl ketone derivatives of monic acid

The synthesis, antibacterial activities, murine pharmacokinetic and infection model data for a range of aryl and heteroaryl ketone derivatives of monic acid (2a) are reported. The best results were found for the 3-furyl and 2-methoxy thiazol-5-yl analogues.

Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity

Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated