123844-17-7Relevant academic research and scientific papers
Electron-Transfer Reactions On Enol-Ethers Induced By Aminium Salts Syntheses of 1,2-Dioxetanes And/Or Ketones
Lopez, Luigi,Troisi, Luigino
, p. 7321 - 7330 (1992)
Thermally stable 4-alkoxy-4-(aryl)spiro 2a-e have been synthesized by reaction of oxygen-saturated methylene chloride solutions of alkoxy(aryl) methylidene adamantanes 1a-e with catalytic amounts of one electron oxidizing agents as tris-p-bromophenyl ammoniumyl and/or tris-o,p-dibromophenyl ammoniumyl hexachloroantimonates (reagents A,B).Similar reactions carried out on 1a-d, under argon-atmosphere, yield adamantyl-arylketones 5a-c together with the corresponding alcohols 6a-b.Both processes most likely involve the formation of radical cation intermediates (1+.), leading to the reaction products through chain electron-transfer mechanisms.
