123860-24-2

Basic information

• Product Name: Pt*((C₆H₅)2PC₅H₄)2Fe*CH₃OC₆H₄CHCHBr=Pt(((C₆H₅)2PC₅H₄)2Fe)(CH₃OC₆H₄CHCHBr)
• Synonyms: Pt*((C₆H₅)2PC₅H₄)2Fe*CH₃OC₆H₄CHCHBr=Pt(((C₆H₅)2PC₅H₄)2Fe)(CH₃OC₆H₄CHCHBr)
• CAS NO: 123860-24-2
• Molecular Weight: 962.545
• Mol File: 123860-24-2.mol

Chemical Properties

• CAS DataBase Reference: Pt*((C₆H₅)2PC₅H₄)2Fe*CH₃OC₆H₄CHCHBr=Pt(((C₆H₅)2PC₅H₄)2Fe)(CH₃OC₆H₄CHCHBr)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt*((C₆H₅)2PC₅H₄)2Fe*CH₃OC₆H₄CHCHBr=Pt(((C₆H₅)2PC₅H₄)2Fe)(CH₃OC₆H₄CHCHBr)(123860-24-2)
• EPA Substance Registry System: Pt*((C₆H₅)2PC₅H₄)2Fe*CH₃OC₆H₄CHCHBr=Pt(((C₆H₅)2PC₅H₄)2Fe)(CH₃OC₆H₄CHCHBr)(123860-24-2)

Safety Data

• Hazardous Substances Data: 123860-24-2(Hazardous Substances Data)

Upstream product

• 6303-59-9 (E)-4-(2-bromo-vinyl)-anisole 
• 27570-08-7 4-(2-bromo-vinyl)-anisole 

Downstream Products

• 123886-28-2 {1,1'-bis(diphenylphosphino)ferrocene}bromo{(E)-2-(4-methoxyphenyl)vinyl}platinum 

Relevant articles and documents

Synthesis and structure of a cationic diplatinum μ-alkylidene μ-hydride complex

The dinuclear μ-alkylidene μ-hydride cation [Pt2(dppf)2(μ-CHCH2Ar)(μ-H)][Br] (2, dppf = Ph2PC5H4FeC5H4PPh 2, Ar = p-MeOC6H4) was obtained unexpectedly from reaction of p-methoxybromostyrene (3) with Pt(dppf)Cl2/NABH4/norbornene and crystallographically characterized. Solutions of the hydride [Pt(dppf)H]2 (7), prepared by deprotonation of the known cation [Pt2(dppf)2H3]+ (6) or by treatment of Pt(dppf)Cl2 with two equiv of LiBEt3H, deposit an insoluble precipitate formulated as [Pt(dppf)H]n (11), which also gives 2 on treatment with 3.

Mapping the reaction pathway in palladium-catalyzed cross-coupling reactions

This paper is concerned with the reaction of palladium complexes of the ligand 1,1′-bis(diphenylphosphino)-ferrocene which have been used to define intermediates in the cross-coupling catalytic cycle. The structure of these intermediates and their interco