123878-18-2 Usage
Chemical Properties
White Solid
Uses
N-Desmethyl (-)-Canadalisol N-Carboxylic Acid Ethyl Ester is an intermediate in the preparation of (-)-Canadalisol (C175195) and (S)-(+)-Canadaline (C175185).
Check Digit Verification of cas no
The CAS Registry Mumber 123878-18-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,3,8,7 and 8 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 123878-18:
(8*1)+(7*2)+(6*3)+(5*8)+(4*7)+(3*8)+(2*1)+(1*8)=142
142 % 10 = 2
So 123878-18-2 is a valid CAS Registry Number.
123878-18-2Relevant articles and documents
Chemical Transformation of Protoberberines. IV. A Novel, Simple Synthesis of (+/-)-Canadaline and a Retroprotoberberine from Tetrahydroberberine
Hanaoka, Miyoji,Nagami, Kazuyoshi,Inoue, Mitsuru,Yasuda, Shingo
, p. 2685 - 2690 (2007/10/02)
Heating of tetrahydroberberine (1) in ethyl chloroformate preferentially afforded the C8-N bond cleavage (4) with small amounts of the C6-N and C14-N bond cleavage products (5 and 6, respectively).The urethane (4) was effe