123883-64-7Relevant academic research and scientific papers
Methyl 2,2-difluoro-2-(fluorosulfonyl)acetate, a difluorocarbene reagent with reactivity comparable to that of trimethylsilyl 2,2-difluoro-2- (fluorosulfonyl)acetate (TFDA)
Eusterwiemann, Steffen,Martinez, Henry,Dolbier, William R.
experimental part, p. 5461 - 5464 (2012/08/07)
Under specific high concentration, high temperature conditions, methyl 2,2-difluoro-2-(fluorosulfonyl)acetate (MDFA) has been found to act as a very efficient source of difluorocarbene, exhibiting carbene reactivity characteristics comparable to those exhibited by trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate (TFDA). For example, in reaction with highly unreactive n-butyl acrylate and using only 2 equiv of MDFA, a yield of 76% of difluorocyclopropane product was obtained after 2 days.
Reactions of Difluoridichloromethane with Hydrocarbons
Schmidt, H.,Burtzlaff, Ch.,Masuhr, H.',Ohl, J.,Pehle, W.,et al.
, p. 751 - 760 (2007/10/02)
The reaction of difluoridichloromethane with different hydrocarbons between 150 deg C and 250 deg C yields the CFCl2-substituted hydrocarbons.Beside it the corresponding chlorides are formed.For the hydrocarbons studied the following sequence of reactivity against difluordichloromethane was found: n-paraffins isoparaffins ca. cycloparaffins alkylaromatics olefines.
