1239024-14-6

Basic information

• Product Name: C₈H₉NO
• Synonyms: C₈H₉NO
• CAS NO: 1239024-14-6
• Molecular Weight: 135.166
• Mol File: 1239024-14-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: C₈H₉NO(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₉NO(1239024-14-6)
• EPA Substance Registry System: C₈H₉NO(1239024-14-6)

Safety Data

• Hazardous Substances Data: 1239024-14-6(Hazardous Substances Data)

Upstream product

• 2156-04-9 4-Vinylphenylboronic acid 
• 1239023-63-2 C₂₇H₁₅F₁₇N₂O₄ 

Downstream Products

• 1268386-98-6 C₁₅H₁₂BrNO 
• 1310486-77-1 C₁₅H₁₂ClNO 
• 1310486-78-2 C₁₆H₁₅NO 
• 1310486-93-1 2-p-tolyl-5-vinylbenzo[d]oxazole 
• 1310486-92-0 2-(4-chlorophenyl)-5-vinylbenzo[d]oxazole 
• 1268390-18-6 C₁₅H₁₀BrNO 

Relevant articles and documents

Rhodium(III)-Catalyzed Redox-Neutral Cascade [3 + 2] Annulation of N-Phenoxyacetamides with Propiolates via C-H Functionalization/Isomerization/Lactonization

A Rh(III)-catalyzed cascade [3 + 2] annulation of N-phenoxyacetamides with propiolates under mild conditions using the internal oxidative O-N bond as the directing group has been achieved. This catalytic system provides a regio- and stereoselective access to benzofuran-2(3H)-ones bearing exocyclic enamino motifs with exclusive Z configuration selectivity, acceptable to good yields and good functional group compatibility. Mechanistic investigations by experimental and density functional theory studies suggest that a consecutive process of C-H functionalization/isomerization/lactonization is likely to be involved in the reaction.

Copper-mediated synthesis of substituted 2-aryl-N-benzylbenzimidazoles and 2-arylbenzoxazoles via C-H functionalization/C-N/C-O bond formation

An efficient method for the transformation of N-benzyl bisarylhydrazones and bisaryloxime ethers to functionalized 2-aryl-N-benzylbenzimidazoles and 2-arylbenzoxazoles is described. The protocol involves a copper(II)-mediated cascade C-H functionalization/C-N/C-O bond formation under neutral conditions. Substrates having either electron-donating or -withdrawing substituents undergo the cyclization to afford the target heterocycles at moderate temperature.

Fluorous tagged N-hydroxy phthalimide for the parallel synthesis of O-aryloxyamines

The parallel synthesis of O-aryloxyamines remains an unfulfilled need in the field of medicinal chemistry and fragment-based approaches. To fill this gap a solution-phase two-step process based on (1) a copper-catalyzed cross-coupling of aryl boronic acid