1239456-68-8Relevant articles and documents
Enantioselective nickel-catalyzed reductive coupling of alkynes and imines
Zhou, Chang-Yue,Zhu, Shou-Fei,Wang, Li-Xin,Zhou, Qi-Lin
supporting information; experimental part, p. 10955 - 10957 (2010/09/17)
The nickel-catalyzed reductive coupling of alkynes and imines with Et 2Zn as a reductant by using electron-rich phosphine ligands has been developed, affording various allylic amines with high yields and excellent chemoselectivities. Chiral induction was also achieved in this reductive coupling reaction when a nickel catalyst containing a chiral spiro phosphine ligand was used.