1239476-45-9Relevant academic research and scientific papers
A domino pericyclic route to polysubstituted salicylic acid derivatives: Four sequential processes from enynones and ketene silyl acetals
Hamura, Toshiyuki,Iwata, Shin,Suzuki, Keisuke
scheme or table, p. 6891 - 6893 (2011/08/08)
Alkenyl alkynyl ketones and ketene silyl acetals (KSAs) undergo regioselective [2+2]-cycloaddition under thermal conditions, triggering domino pericyclic reactions en route to various poly-substituted salicylic acid derivatives.
Siloxy(trialkoxy)ethene undergoes regioselective [2+2] cycloaddition to ynones and ynoates en route to functionalized cyclobutenediones
Iwata, Shin,Hamura, Toshiyuki,Suzuki, Keisuke
supporting information; experimental part, p. 5316 - 5318 (2010/11/18)
Regioselective [2+2] cycloaddition of ynones or ynoates to siloxy(trialkoxy)ethene (KSA) is described. A siloxy group on the KSA directs the perfect regioselectivity, allowing rapid construction of various functionalized cyclobutenedione derivatives.
