1239610-25-3Relevant academic research and scientific papers
Urea/transition-metal cooperative catalyst for anti-selective asymmetric nitroaldol reactions
Lang, Kai,Park, Jongwoo,Hong, Sukwon
, p. 1620 - 1624 (2012)
A cooperative catalyst that features urea H-bonding and a cobalt center was developed for anti-selective asymmetric Henry reactions (see scheme). The H-bonds of urea play a crucial role in the improvement in yield (from 30 % to 84 %), enantioselectivity (
Catalytic asymmetric henry reaction of nitroalkanes and aldehydes catalyzed by a chiral N, N '-dioxide/Cu(I) complex
Mei, Hongjiang,Xiao, Xiao,Zhao, Xiaohu,Fang, Bing,Liu, Xiaohua,Lin, Lili,Feng, Xiaoming
, p. 2272 - 2280 (2015/03/18)
An easily available N,N'-dioxide/Cu(I) complex has been developed for the catalytic asymmetric nitroaldol (Henry) reaction of aldehydes with nitroethane. Under mild reaction conditions, a series of substituted aromatic, heteroaromatic and α,β-unsaturated
