123966-63-2

Upstream product

• 123966-61-0 (+/-)-3t-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone 
• 1073-13-8 4,4-dimethylcyclohexenone 
• 7205-91-6 phenylthiomethyl chloride 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 123966-68-7 (+/-)-3c-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal 
• 123966-68-7 (+/-)-3t-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone ethane-1,2-diyl acetal 
• 123966-74-5 (+/-)-(2Ξ)-3c-allyl-2r-<(Ξ)-benzenesulfinylmethyl>-4,4-dimethyl-cyclohexanone ethane-1,2-diyl acetal 
• 123966-74-5 (+/-)-(2Ξ)-3t-allyl-2r-<(Ξ)-benzenesulfinylmethyl>-4,4-dimethyl-cyclohexanone ethane-1,2-diyl acetal 
• 123966-61-0 (+/-)-3c-allyl-4,4-dimethyl-2r-phenylsulfanylmethyl-cyclohexanone 
• 123966-78-9 (+/-)-8c-benzenesulfonyl-6t-hydroxy-4,4-dimethyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal 
• 123966-78-9 (+/-)-8t-benzenesulfonyl-6c-hydroxy-4,4-dimethyl-(4ar,8at)-octahydro-naphthalen-1-one ethane-1,2-diyl acetal 
• 123966-64-3 (+/-)-3c-benzenesulfonyl-2t-hydroxymethyl-7,7-dimethyl-(3ar,7ac)-octahydro-inden-4-one ethane-1,2-diyl acetal 
• 123966-64-3 (+/-)-3c-benzenesulfonyl-2c-hydroxymethyl-7,7-dimethyl-(3ar,7ac)-octahydro-inden-4-one ethane-1,2-diyl acetal 
• 123966-64-3 (+/-)-3c-benzenesulfonyl-2t-hydroxymethyl-7,7-dimethyl-(3ar,7at)-octahydro-inden-4-one ethane-1,2-diyl acetal 
• 123966-64-3 (+/-)-3c-benzenesulfonyl-2c-hydroxymethyl-7,7-dimethyl-(3ar,7at)-octahydro-inden-4-one ethane-1,2-diyl acetal 
• 123966-76-7 (+/-)-3c-benzenesulfonyl-2t-methoxymethyl-7,7-dimethyl-(3ar,7at)-octahydro-inden-4-one 
• 123966-76-7 (+/-)-3c-benzenesulfonyl-2t-methoxymethyl-7,7-dimethyl-(3ar,7ac)-octahydro-inden-4-one 
• 123966-76-7 (+/-)-3c-benzenesulfonyl-2c-methoxymethyl-7,7-dimethyl-(3ar,7at)-octahydro-inden-4-one 

Relevant academic research and scientific papers

FORSKOLIN: SOME STUDIES ON RING B FORMING REACTIONS

Cyclization of the unsaturated sulfoxides 18b, 18c under Pummerer conditions provided the six-membered products 20a and 21a, whereas base-catalyzed cyclization of the stereoisomeric epoxysulfones 16a, 16b and 17a, 17b led exclusively to the five-membered